Seasonal changes in groundwater quality and its suitability for drinking and irrigation uses
DOI:
https://doi.org/10.53550/Keywords:
Correlation matrix, Drinking, Groundwater quality, Irrigation, Normality, Seasonal variability, t-test, US Salinity Laboratory diagram, World Health OrganizationAbstract
This study deals with evaluation of spatial and short-term temporal variation of groundwater quality during pre- and post-monsoon seasons in Jaipur district of Rajasthan by using statistical techniques, i.e. box and whisker plots, correlation matrices, and t-test, to the data collected for 153 sampling sites. In addition, this study assesses the groundwater quality to find its aptness for drinking and irrigation needs by comparing with drinking water standards prescribed by World Health Organization (WHO), and by plotting United States Salinity Laboratory (USSL) diagrams. Data of 13 groundwater quality parameters, i.e. calcium, magnesium, sodium, potassium, sulphate, chloride, nitrate, carbonate, bicarbonate, fluoride, Total Dissolved Solids (TDS), Electrical Conductivity (EC) and pH, were analyzed for two seasons of four-year (2006-2009) period. The box and whisker plots revealed presence of non-normality in spatial series of almost all the parameters due to right-skewed distributions in both seasons. The box-whisker plots also revealed linkages between the water quality parameters and rainfall recharge occurring in aquifer system. Correlation matrices depicted a very strong linear relationship between seven pairs of the groundwater quality parameters, i.e. EC-TDS, EC-sodium, EC-chloride, TDS-sodium, TDS-chloride, pH-carbonate, and sodium-chloride during both seasons. However, magnitude of correlation was relatively less during the post-monsoon season as compared to pre-monsoon season. Results of t-test revealed a significant change in the mean concentrations of six parameters, i.e. pH, sodium, calcium, bicarbonate, nitrate, and fluoride at 5% significance level during pre-monsoon season in 4-year period. On the other hand, during post-monsoon season, only nitrate showed a significant change in 4- year period. Moreover, the groundwater quality in the area is not found safe for drinking purpose based on WHO standards as well as for irrigation use based on USSL diagrams. This finding emphasizes the need of formulating adequate policies in order to preserve and improve the groundwater quality in the area.
References
Adhikary, P.P, Dash, C.J., Sarangi, A. and Singh, D.K. 2014. Hydrochemical characterization and spatial distribution of fluoride in groundwater of Delhi state. Ind. J. Soil Cons., 42(2): 170-173.
Adhikary, P.P. and Biswas, H. 2011. Geospatial assessment of groundwater quality in Datia district of Bundelkhand. Ind. J. Soil Cons., 39(2): 108-116.
Agca, N. 2014. Spatial variability of groundwater quality and its suitability for drinking and irrigation in the Amik Plain (South Turkey). Environ. Earth. Sci., 72(10): 4115-4130.
CGWB. 2007. Groundwater Scenario: Jaipur District, Rajasthan. District Groundwater Brochure, Central Groundwater Board (CGWB), Western Region, Jaipur, Ministry of Water Resources, Government of India, 25 p.
Chan, H.J. 2001. Effect of land use and urbanization on hydrochemistry and contamination of groundwater from Taejon area, Korea. J. Hydrol., 253: 194-210.
Trupti Kamble et al./Ind. J. Soil Cons. 44(3): 266-275, 2016 275
Dhak, S.M., Machiwal, D., Purohit, R.C., Yadav, K.K. and Singh, P.K. 2012. Evaluating suitability of groundwater for drinking and irrigation purposes using conventional techniques. Hydrol. J., 35(1&2): 40-51.
Elci, A. and Polat, R. 2011. Assessment of the statistical significance of seasonal groundwater quality change in a karstic aquifer system near Izmir-Turkey. Environ. Monit. Assess., 172(1-4): 445-62.
Helena,B., Pardo,R.,Vega, M.,Barrado,E., Fernandez,J.M. and Fernandez, L. 2000. Temporal evolution of ground water composition in an alluvial aquifer (Pisuerga River, Spain) by principal component analysis. Wat. Res., 34: 807-816.
Jothivenkatachalam, K., Nithya, A. and Chandra Mohan, S. 2010. Correlation analysis of drinking water quality in and around Perur block of Coimbatore District, Tamil Nadu, India. Rasayan J. Chem., 3(4): 649-654.
Kamra, S.K., Khajanchi Lal, Singh, O.P. and Boonstra, J. 2002. Effect of pumping on temporal changes in groundwater quality. Agric. Water Manage., 56: 169-178.
Karanth, K.R. 1987. Ground Water Assessment: Development and Management. Tata McGraw-Hill Publishing Company Limited, New Delhi, pp 720.
Kumar, N. and Sinha, D.K. 2010. Drinking water quality management through correlation studies among various physicochemical parameters: a case study. Int. J. Environ. Sci., 1(2): 253-259.
Machiwal, D. and Jha, M.K. 2015. Identifying sources of groundwater contamination in a hard-rock aquifer system using multivariate statistical analyses and GIS-based geostatistical modeling techniques. J. Hydrol: Reg. Stud., http://dx.doi.org/10.1016/j.ejrh. 2014.11.005.
Machiwal, D. and Jha, M.K. 2010. Tools and techniques for water quality interpretation. In: Krantzberg, G., Tanik, A., Antunes do Carmo, J.S., Indarto, A. and Ekdal, A. (Editors-in-Chief), Advances in Water Quality Control, Scientific Research Publishing, Inc., California, USA, pp. 211-252.
Machiwal, D. and Jha, M.K. 2012. Hydrologic Time Series Analysis: Theory and Practice. Capital Publishing Company, New Delhi, India and Springer, Germany, 303 p.
Machiwal, D., Jha, M.K. and Mal, B.C. 2011. GIS-based assessment and characterization of groundwater quality in a hard-rock hilly terrain of Western India. Environ. Monit. Assess., 174(1-4): 645-663.
Patil, V.T. and Patil, P.R. 2010. Physicochemical analysis of selected groundwater samples of Amalner town in Jalgaon district, Maharashtra, India, Electron. J. Ch., 7(1): 111-116.
Sara, M.N. and Gibbons, R. 1991. Organization and Analysis of Water Quality Data. In: D.M. Nielsen (Editor), Practical Handbook of Ground-Water Monitoring, Lewis Publishers, Michigan, USA, pp. 541-588.
Snedecor, G.W. and Cochran, W.G. 1980. Statistical Methods. Iowa State University Press, Ames, Iowa.
Tatawat, R.K. and Chandel, C.P. 2008. A hydrochemical profile for assessing the groundwater quality of Jaipur City. Environ. Monit. Assess., 143: 337-343.
WHO. 2006. Guidelines for drinking-water quality: First addendum to third edition. Recommendations (Vol. 1, pp. 515). Geneva: World Health Organization (WHO).
USEPA. 2006. Data Quality Assessment: Statistical Methods for Practitioners. Guidance Document EPA QA/G-9S, United States Environmental ProtectionAgency (USEPA), Office of Environmental Information, Washington D.C.
USSL. 1954. Diagnosis and improvement of saline and alkali soils, Handbook 60, USDA. pp. 160.



